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Diols Diols (MPD & ND)

MPD

MPD structural formula
CAS No. 4457-71-0

MPD (3-Methyl-1,5-pentanediol) is a diol which is an isomer of 1,6-hexanediol. MPD is amorphous, giving excellent properties to polyurethanes.: outstanding softness, high transparency and compatibility, owing to the methyl branch in the middle of its structure.

ND

ND structural formula
CAS No. 3937-56-2

ND (1,9-nonanediol) is a C9 diol with a straight-chain alkyl group. Due to its long chain length, it has a relatively high melting point, but its viscosity drops sharply when the temperature reaches around 60°C.

Image: Diol top image

Features

MPD

Softness
Kuraray Polyol inhibits cohesion. This allows for increased operating efficiency.

Hydrolysis resistance
Hydrolysis resistance is good; MPD can inhibit the hydrolysis resistance of polyurethanes.

ND

Appropriate crystallinity
By moderately disrupting orientation (crystallinity), it imparts strength and flexibility to polyurethane.

Appearance Diol

Left:MPD at room temp.
Right:ND heating at 60°C


Hydrolysis resistance (MPD)

The hydrolysis resistance of PU resin from MPD-based polyester polyol is high even MPD portion is small as an ingredient of polyester polyol.

Graph: Hydrolysis resistance

Appropriate crystallinity (ND)

Compared to diols with even carbon numbers, molecular chains are less likely to be oriented, and crystallinity is appropriately suppressed, resulting in a lower melting point. The moderate crystallinity gives the resin strength and flexibility and improves transparency.

Graph: Melting point

Applications

MPD

  • Polyurethanes (polyols, chain extenders)
  • Solvents
  • Acrylate Monomer

ND

  • Polyurethanes (polyols, chain extenders)
  • Polyester
  • UV monomer, oligomer
  • Acrylate Monomer
Running shoes

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